If UserGroups has a one to many relationship with UserGroupPrices table, then in EF, once the relationship is defined in code like:
//In UserGroups Model
public List<UserGroupPrices> UserGrpPriceList {get;set;}
//In UserGroupPrices model
public UserGroups UserGrps {get;set;}
You can pull the left joined result set by simply this:
var list = db.UserGroupDbSet.ToList();
assuming your DbSet for the left table is UserGroupDbSet, which will include the UserGrpPriceList, which is a list of all associated records from the right table.