Does the form you are trying to emulate have two fields, username and password?
If so, this line:
postData.Add("username", "password");
is not correct.
you would need two lines like:
postData.Add("username", "Moose");
postData.Add("password", "NotMoosespasswordreally");
Edit:
Okay, since that is not the problem, one way to tackle this is to use something like Fiddler or Wireshark to watch what is being sent to the web server from the browser successfully, then compare that to what is being sent from your code. If you are going to a normal port 80 from .Net, Fiddler will still capture this traffic.
There is probably some other hidden field on the form that the web server is expecting that you are not sending.