[c#] How to get first object out from List<Object> using Linq

You can do

Component depCountry = lstComp
                       .Select(x => x.ComponentValue("Dep"))
                       .FirstOrDefault();

Alternatively if you are wanting this for the entire dictionary of values, you can even tie it back to the key

var newDictionary = dic.Select(x => new 
            {
               Key = x.Key,
               Value = x.Value.Select( y => 
                      {
                          depCountry = y.ComponentValue("Dep")
                      }).FirstOrDefault()
             }
             .Where(x => x.Value != null)
             .ToDictionary(x => x.Key, x => x.Value());

This will give you a new dictionary. You can access the values

var myTest = newDictionary[key1].depCountry     

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