In mysqli_query(first parameter should be connection,your sql statement) so
$connetion_name=mysqli_connect("localhost","root","","web_table") or die(mysqli_error());
mysqli_query($connection_name,'INSERT INTO web_formitem (ID, formID, caption, key, sortorder, type, enabled, mandatory, data) VALUES (105, 7, Tip izdelka (6), producttype_6, 42, 5, 1, 0, 0)');
but best practice is
$connetion_name=mysqli_connect("localhost","root","","web_table") or die(mysqli_error());
$sql_statement="INSERT INTO web_formitem (ID, formID, caption, key, sortorder, type, enabled, mandatory, data) VALUES (105, 7, Tip izdelka (6), producttype_6, 42, 5, 1, 0, 0)";
mysqli_query($connection_name,$sql_statement);