If using 4.5+ Framework I would use ReadOnlyDictionary (also ReadOnly Collection for lists) to do readonly mappings/constants. It's implemented in the following way.
static class SomeClass
{
static readonly ReadOnlyDictionary<string,int> SOME_MAPPING
= new ReadOnlyDictionary<string,int>(
new Dictionary<string,int>()
{
{ "One", 1 },
{ "Two", 2 }
}
)
}