Finally, Works!
Put smtpClient.UseDefaultCredentials = false;
after smtpClient.Credentials = credentials;
then problem resolved!
SmtpClient smtpClient = new SmtpClient(smtpServerName);
System.Net.NetworkCredential credentials = new System.Net.NetworkCredential(smtpUName, smtpUNamePwd);
smtpClient.Credentials = credentials;
smtpClient.UseDefaultCredentials = false; <-- Set This Line After Credentials
smtpClient.Send(mailMsg);
smtpClient = null;
mailMsg.Dispose();