int arr[10] = {0, 5, 3, 64};
arr[4] = 5;
EDIT: So I was asked to explain what's happening when you do:
int arr[10] = {0, 5, 3, 64};
you create an array with 10 elements and you allocate values for the first 4 elements of the array.
Also keep in mind that arr starts at index arr[0] and ends at index arr[9] - 10 elements
arr[0] has value 0;
arr[1] has value 5;
arr[2] has value 3;
arr[3] has value 64;
after that the array contains garbage values / zeroes because you didn't allocated any other values
But you could still allocate 6 more values so when you do
arr[4] = 5;
you allocate the value 5 to the fifth element of the array.
You could do this until you allocate values for the last index of the arr that is arr[9];
Sorry if my explanation is choppy, but I have never been good at explaining things.