Well, you are clearing the textbox right before you check if it's empty
/* !! This clears the textbox BEFORE you check if it's empty */
MaterialTextBox.Clear();
HoursNumericUpDown.Value = HoursNumericUpDown.Minimum;
MarkNumericUpDown.Value = MarkNumericUpDown.Minimum;
if (String.IsNullOrEmpty(MaterialTextBox.Text))
{
MessageBox.Show("Enter Material Name Please.", "Error", MessageBoxButtons.OK, MessageBoxIcon.Warning);
//dataGridView1.Rows.Clear();
}