You can write as follows:
SqlCommand check_User_Name = new SqlCommand("SELECT * FROM Table WHERE ([user] = '" + txtBox_UserName.Text + "') ", conn);
if (check_User_Name.ExecuteScalar()!=null)
{
int UserExist = (int)check_User_Name.ExecuteScalar();
if (UserExist > 0)
{
//Username Exist
}
}