Use NameValuedCollection.
Good starting point is here. Straight from the link.
System.Collections.Specialized.NameValueCollection myCollection
= new System.Collections.Specialized.NameValueCollection();
myCollection.Add(“Arcane”, “http://arcanecode.com”);
myCollection.Add(“PWOP”, “http://dotnetrocks.com”);
myCollection.Add(“PWOP”, “http://dnrtv.com”);
myCollection.Add(“PWOP”, “http://www.hanselminutes.com”);
myCollection.Add(“TWIT”, “http://www.twit.tv”);
myCollection.Add(“TWIT”, “http://www.twit.tv/SN”);