I'd wrap the dictionary in another class:
public class MyListDictionary
{
private Dictionary<string, List<string>> internalDictionary = new Dictionary<string,List<string>>();
public void Add(string key, string value)
{
if (this.internalDictionary.ContainsKey(key))
{
List<string> list = this.internalDictionary[key];
if (list.Contains(value) == false)
{
list.Add(value);
}
}
else
{
List<string> list = new List<string>();
list.Add(value);
this.internalDictionary.Add(key, list);
}
}
}