You have two easy ways to do this. Jay has covered the accurate way of checking from the center of the ball.
The easier way is to use a rectangle bounding box, set the size of your box to be 80% the size of the ball, and you'll simulate collision pretty well.
Add a method to your ball class:
public Rectangle getBoundingRect()
{
int ballHeight = (int)Ball.Height * 0.80f;
int ballWidth = (int)Ball.Width * 0.80f;
int x = Ball.X - ballWidth / 2;
int y = Ball.Y - ballHeight / 2;
return new Rectangle(x,y,ballHeight,ballWidth);
}
Then, in your loop:
// Checks every ball against every other ball.
// For best results, split it into quadrants like Ryan suggested.
// I didn't do that for simplicity here.
for (int i = 0; i < balls.count; i++)
{
Rectangle r1 = balls[i].getBoundingRect();
for (int k = 0; k < balls.count; k++)
{
if (balls[i] != balls[k])
{
Rectangle r2 = balls[k].getBoundingRect();
if (r1.Intersects(r2))
{
// balls[i] collided with balls[k]
}
}
}
}