I think a DTO can be a POCO. DTO is more about the usage of the object while POCO is more of the style of the object (decoupled from architectural concepts).
One example where a POCO is something different than DTO is when you're talking about POCO's inside your domain model/business logic model, which is a nice OO representation of your problem domain. You could use the POCO's throughout the whole application, but this could have some undesirable side effect such a knowledge leaks. DTO's are for instance used from the Service Layer which the UI communicates with, the DTO's are flat representation of the data, and are only used for providing the UI with data, and communicating changes back to the service layer. The service layer is in charge of mapping the DTO's both ways to the POCO domain objects.
Update Martin Fowler said that this approach is a heavy road to take, and should only be taken if there is a significant mismatch between the domain layer and the user interface.