This Work perfectly for me to create RowNumber when we have more than one column. In this case two column.
SELECT @row_num := IF(@prev_value= concat(`Fk_Business_Unit_Code`,`NetIQ_Job_Code`), @row_num+1, 1) AS RowNumber,
`Fk_Business_Unit_Code`,
`NetIQ_Job_Code`,
`Supervisor_Name`,
@prev_value := concat(`Fk_Business_Unit_Code`,`NetIQ_Job_Code`)
FROM (SELECT DISTINCT `Fk_Business_Unit_Code`,`NetIQ_Job_Code`,`Supervisor_Name`
FROM Employee
ORDER BY `Fk_Business_Unit_Code`, `NetIQ_Job_Code`, `Supervisor_Name` DESC) z,
(SELECT @row_num := 1) x,
(SELECT @prev_value := '') y
ORDER BY `Fk_Business_Unit_Code`, `NetIQ_Job_Code`,`Supervisor_Name` DESC