Depending on the compelexity of your Account object, I would recomend either XML or Flat file.
If there are just a couple of values to store for each account, you could store them on a properties file, like this:
account.1.somekey=Some value
account.1.someotherkey=Some other value
account.1.somedate=2009-12-21
account.2.somekey=Some value 2
account.2.someotherkey=Some other value 2
... and so forth. Reading from a properties file should be easy, as it maps directly to a string dictionary.
As to where to store this file, the best choise would be to store into AppData folder, inside a subfolder for your program. This is a location where current users will always have access to write, and it's kept safe from other users by the OS itself.