If you installed new Codeigniter, please check if you added .htaccess file on root directory. If you didn't add it yet, please add it. You can put default content it the .htaccess file like below.
<IfModule mod_rewrite.c>
RewriteEngine On
RewriteBase /
#Removes access to the system folder by users.
#Additionally this will allow you to create a System.php controller,
#previously this would not have been possible.
#'system' can be replaced if you have renamed your system folder.
RewriteCond %{REQUEST_URI} ^system.*
RewriteRule ^(.*)$ /index.php?/$1 [L]
#When your application folder isn't in the system folder
#This snippet prevents user access to the application folder
#Submitted by: Fabdrol
#Rename 'application' to your applications folder name.
RewriteCond %{REQUEST_URI} ^application.*
RewriteRule ^(.*)$ /index.php?/$1 [L]
#Checks to see if the user is attempting to access a valid file,
#such as an image or css document, if this isn't true it sends the
#request to index.php
RewriteCond %{REQUEST_FILENAME} !-f
RewriteCond %{REQUEST_FILENAME} !-d
RewriteRule ^(.*)$ index.php?/$1 [L]
</IfModule>
<IfModule !mod_rewrite.c>
# If we don't have mod_rewrite installed, all 404's
# can be sent to index.php, and everything works as normal.
# Submitted by: ElliotHaughin
ErrorDocument 404 /index.php
</IfModule>