Use services (start -> run -> services.msc) and look for the postgresql-[version] service.
Adding to the first, because in a different comment you've said the service isn't there. It is possible to download a standalone pgAdmin so you can connect to an external PostgreSQL database. It would seem you have done such a thing, or explicitly chosen to not add the service. Just try the One Click Installer, which still allows proper configuration of installation directory despite its name.