try this...
public class Student
{
public int Grade { get; set; }
public string Name { get; set; }
public override string ToString()
{
return string.Format("Name{0} : Grade{1}", Name, Grade);
}
}
class Program
{
static void Main(string[] args)
{
List<Student> listStudents = new List<Student>();
listStudents.Add(new Student() { Grade = 10, Name = "Pedro" });
listStudents.Add(new Student() { Grade = 10, Name = "Luana" });
listStudents.Add(new Student() { Grade = 10, Name = "Maria" });
listStudents.Add(new Student() { Grade = 11, Name = "Mario" });
listStudents.Add(new Student() { Grade = 15, Name = "Mario" });
listStudents.Add(new Student() { Grade = 10, Name = "Bruno" });
listStudents.Add(new Student() { Grade = 10, Name = "Luana" });
listStudents.Add(new Student() { Grade = 11, Name = "Luana" });
listStudents.Add(new Student() { Grade = 22, Name = "Maria" });
listStudents.Add(new Student() { Grade = 55, Name = "Bruno" });
listStudents.Add(new Student() { Grade = 77, Name = "Maria" });
listStudents.Add(new Student() { Grade = 66, Name = "Maria" });
listStudents.Add(new Student() { Grade = 88, Name = "Bruno" });
listStudents.Add(new Student() { Grade = 42, Name = "Pedro" });
listStudents.Add(new Student() { Grade = 33, Name = "Bruno" });
listStudents.Add(new Student() { Grade = 33, Name = "Luciana" });
listStudents.Add(new Student() { Grade = 17, Name = "Maria" });
listStudents.Add(new Student() { Grade = 25, Name = "Luana" });
listStudents.Add(new Student() { Grade = 25, Name = "Pedro" });
listStudents.GroupBy(g => g.Name).OrderBy(g => g.Key).SelectMany(g => g.OrderByDescending(x => x.Grade)).ToList().ForEach(x => Console.WriteLine(x.ToString()));
}
}