I was looking also a sorting fields that has letter prefix. Here is what i found out the solution. This might help who is looking for the same solution.
Field Values:
FL01,FL02,FL03,FL04,FL05,...FL100,...FL123456789
select SUBSTRING(field,3,9) as field from table order by SUBSTRING(field,3,10)*1 desc
SUBSTRING(field,3,9)
i put 9 because 9 is way enough for me to hold max 9 digits integer values.
So the result will be 123456789 123456788 123456787 ... 100 99 ... 2 1