Certainly the credit goes to @Harvey Kwok here, but I just wanted to add this example because in my case I wanted to get an actual List of UserPrincipals. It's probably more efficient to filter this query upfront, but in my small environment, it's just easier to pull everything and then filter as needed later from my list.
Depending on what you need, you may not need to cast to DirectoryEntry, but some properties are not available from UserPrincipal.
using (var searcher = new PrincipalSearcher(new UserPrincipal(new PrincipalContext(ContextType.Domain, Environment.UserDomainName))))
{
List<UserPrincipal> users = searcher.FindAll().Select(u => (UserPrincipal)u).ToList();
foreach(var u in users)
{
DirectoryEntry d = (DirectoryEntry)u.GetUnderlyingObject();
Console.WriteLine(d.Properties["GivenName"]?.Value?.ToString() + d.Properties["sn"]?.Value?.ToString());
}
}