At the top first set up database connection as follow:
<?php
$mysqli = new mysqli("localhost", "username", "password", "database") or die($this->mysqli->error);
$query= $mysqli->query("SELECT PcID from PC");
?>
Then include the following code in HTML inside form
<select name="selected_pcid" id='selected_pcid'>
<?php
while ($rows = $query->fetch_array(MYSQLI_ASSOC)) {
$value= $rows['id'];
?>
<option value="<?= $value?>"><?= $value?></option>
<?php } ?>
</select>
However, if you are using materialize css or any other out of the box css, make sure that select field is not hidden or disabled.