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I know this question is old but here is how I solved it.
I copied the openssl.cnf file from the bin directory to the parent directory which is C:/Openssl/openssl.cnf instead of C:/Openssl/bin/openssl.cnf and worked fine.
openssl.cnf
bin
C:/Openssl/openssl.cnf
C:/Openssl/bin/openssl.cnf