I doubt this is good practice but it's working locally. I'll update this if it fails when I publish/deploy (to an IIS web service).
Step 1 - Add this assembly to the top of your class (in my case, controller class):
using Microsoft.Extensions.Configuration;
Step 2 - Add this or something like it:
var config = new ConfigurationBuilder()
.SetBasePath(Directory.GetCurrentDirectory())
.AddJsonFile("appsettings.json").Build();
Step 3 - Call your key's value by doing this (returns string):
config["NameOfYourKey"]