split_part()
does what you want in one step:
SELECT split_part(col, ',', 1) AS col1
, split_part(col, ',', 2) AS col2
, split_part(col, ',', 3) AS col3
, split_part(col, ',', 4) AS col4
FROM tbl;
Add as many lines as you have items in col
(the possible maximum). Columns exceeding data items will be empty strings (''
).