Using NAT (the default) this is not possible. Bridged Networking should allow it. If bridged does not work for you (this may be the case when your network adminstration does not allow multiple IP addresses on one physical interface), you could try 'Host-only networking' instead.
For configuration of Host-only here is a quote from the vbox manual(which is pretty good). http://www.virtualbox.org/manual/ch06.html:
For host-only networking, like with internal networking, you may find the DHCP server useful that is built into VirtualBox. This can be enabled to then manage the IP addresses in the host-only network since otherwise you would need to configure all IP addresses statically.
In the VirtualBox graphical user interface, you can configure all these items in the global settings via "File" -> "Settings" -> "Network", which lists all host-only networks which are presently in use. Click on the network name and then on the "Edit" button to the right, and you can modify the adapter and DHCP settings.