The other answers here are correct too, but I find the following steps to be the easiest:
Just download Xcode 4.6.3 from the dev center link that says "Looking for an older version of Xcode?" (currently points here) and mount the dmg.
Then in terminal, copy the SDK files over:
cp -R /Volumes/Xcode/Xcode.app/Contents/Developer/Platforms/iPhoneOS.platform/Developer/SDKs/iPhoneOS6.1.sdk /Applications/Xcode.app/Contents/Developer/Platforms/iPhoneOS.platform/Developer/SDKs/
Finally, relaunch Xcode and you're done.