After attempting all of the above solutions to eliminate the "curl: (60) SSL certificate problem: unable to get local issuer certificate" error, the solution that finally worked for me on OSX 10.9 was:
Locate the curl certificate PEM file location 'curl-config --ca' -- > /usr/local/etc/openssl/cert.pem
Use the folder location to identify the PEM file 'cd /usr/local/etc/openssl'
Create a backup of the cert.pem file 'cp cert.pem cert_pem.bkup'
Download the updated Certificate file from the curl website 'sudo wget http://curl.haxx.se/ca/cacert.pem'
Copy the downloaded PEM file to replace the old PEM file 'cp cacert.pem cert.pem'
This is a modified version of a solution posted to correct the same issue in Ubuntu found here:
https://serverfault.com/questions/151157/ubuntu-10-04-curl-how-do-i-fix-update-the-ca-bundle