You can use:
PyXML:
from xml.dom.ext.reader import Sax2
from xml import xpath
doc = Sax2.FromXmlFile('foo.xml').documentElement
for url in xpath.Evaluate('//@Url', doc):
print url.value
libxml2:
import libxml2
doc = libxml2.parseFile('foo.xml')
for url in doc.xpathEval('//@Url'):
print url.content