[python] Real time face detection OpenCV, Python

Your line:

img = cv2.rectangle(img,(x,y),(x+w,y+h),(255,0,0),2) 

will draw a rectangle in the image, but the return value will be None, so img changes to None and cannot be drawn.

Try

cv2.rectangle(img,(x,y),(x+w,y+h),(255,0,0),2)