It's probably best to use the Python Image Library to do this which I'm afraid is a separate download.
The easiest way to do what you want is via the load() method on the Image object which returns a pixel access object which you can manipulate like an array:
from PIL import Image
im = Image.open('dead_parrot.jpg') # Can be many different formats.
pix = im.load()
print im.size # Get the width and hight of the image for iterating over
print pix[x,y] # Get the RGBA Value of the a pixel of an image
pix[x,y] = value # Set the RGBA Value of the image (tuple)
im.save('alive_parrot.png') # Save the modified pixels as .png
Alternatively, look at ImageDraw which gives a much richer API for creating images.