With 4 lines, I import a rss to an array.
$feed = implode(file('http://yourdomains.com/feed.rss'));
$xml = simplexml_load_string($feed);
$json = json_encode($xml);
$array = json_decode($json,TRUE);
For a more complex solution
$feed = new DOMDocument();
$feed->load('file.rss');
$json = array();
$json['title'] = $feed->getElementsByTagName('channel')->item(0)->getElementsByTagName('title')->item(0)->firstChild->nodeValue;
$json['description'] = $feed->getElementsByTagName('channel')->item(0)->getElementsByTagName('description')->item(0)->firstChild->nodeValue;
$json['link'] = $feed->getElementsByTagName('channel')->item(0)->getElementsByTagName('link')->item(0)->firstChild->nodeValue;
$items = $feed->getElementsByTagName('channel')->item(0)->getElementsByTagName('item');
$json['item'] = array();
$i = 0;
foreach($items as $key => $item) {
$title = $item->getElementsByTagName('title')->item(0)->firstChild->nodeValue;
$description = $item->getElementsByTagName('description')->item(0)->firstChild->nodeValue;
$pubDate = $item->getElementsByTagName('pubDate')->item(0)->firstChild->nodeValue;
$guid = $item->getElementsByTagName('guid')->item(0)->firstChild->nodeValue;
$json['item'][$key]['title'] = $title;
$json['item'][$key]['description'] = $description;
$json['item'][$key]['pubdate'] = $pubDate;
$json['item'][$key]['guid'] = $guid;
}
echo json_encode($json);