[c] When is assembly faster than C?

I have an operation of transposition of bits that needs to be done, on 192 or 256 bits every interrupt, that happens every 50 microseconds.

It happens by a fixed map(hardware constraints). Using C, it took around 10 microseconds to make. When I translated this to Assembler, taking into account the specific features of this map, specific register caching, and using bit oriented operations; it took less than 3.5 microsecond to perform.

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