Where does the variable results come from?
This block:
foreach (People p in ppl.results) {
list.Add(results.name);
list.Add(results.email);
list2d.Add(list);
}
Should probably read more like:
foreach (People p in ppl.results) {
var list = new List<string>();
list.Add(p.name);
list.Add(p.email);
list2d.Add(list);
}