String[] ops = str.split("\\s*[a-zA-Z]+\\s*");
String[] notops = str.split("\\s*[^a-zA-Z]+\\s*");
String[] res = new String[ops.length+notops.length-1];
for(int i=0; i<res.length; i++) res[i] = i%2==0 ? notops[i/2] : ops[i/2+1];
This should do it. Everything nicely stored in res
.