To get started with dotnet core, SqlServer and EF core the below DBContextOptionsBuilder would sufice and you do not need to create App.config file. Do not forget to change the sever address and database name in the below code.
protected override void OnConfiguring(DbContextOptionsBuilder options)
=> options.UseSqlServer(@"Server=(localdb)\MSSQLLocalDB;Database=TestDB;Trusted_Connection=True;");
To use the EF core SqlServer provider and compile the above code install the EF SqlServer package
dotnet add package Microsoft.EntityFrameworkCore.SqlServer
After compilation before running the code do the following for the first time
dotnet tool install --global dotnet-ef
dotnet add package Microsoft.EntityFrameworkCore.Design
dotnet ef migrations add InitialCreate
dotnet ef database update
To run the code
dotnet run