This modification of a_horse_with_no_name's answer will give you the blocking queries in addition to just the blocked sessions:
SELECT
activity.pid,
activity.usename,
activity.query,
blocking.pid AS blocking_id,
blocking.query AS blocking_query
FROM pg_stat_activity AS activity
JOIN pg_stat_activity AS blocking ON blocking.pid = ANY(pg_blocking_pids(activity.pid));