The ASPX code will look something like this:
<asp:RadioButtonList ID="rblist1" runat="server">
<asp:ListItem Text ="Item1" Value="1" />
<asp:ListItem Text ="Item2" Value="2" />
<asp:ListItem Text ="Item3" Value="3" />
<asp:ListItem Text ="Item4" Value="4" />
</asp:RadioButtonList>
<asp:Button ID="btn1" runat="server" OnClick="Button1_Click" Text="select value" />
And the code behind:
protected void Button1_Click(object sender, EventArgs e)
{
string selectedValue = rblist1.SelectedValue;
Response.Write(selectedValue);
}