Here's one way to do it—there are many others:
bool b[4];
int v = 7; // number to dissect
for (int j = 0; j < 4; ++j)
b [j] = 0 != (v & (1 << j));
It is hard to understand why use of a loop is not desired, but it is easy enough to unroll the loop:
bool b[4];
int v = 7; // number to dissect
b [0] = 0 != (v & (1 << 0));
b [1] = 0 != (v & (1 << 1));
b [2] = 0 != (v & (1 << 2));
b [3] = 0 != (v & (1 << 3));
Or evaluating constant expressions in the last four statements:
b [0] = 0 != (v & 1);
b [1] = 0 != (v & 2);
b [2] = 0 != (v & 4);
b [3] = 0 != (v & 8);