XmlTextWriter xmlw = new XmlTextWriter(@"C:\WINDOWS\Temp\exm.xml",System.Text.Encoding.UTF8);
xmlw.WriteStartDocument();
xmlw.WriteStartElement("examtimes");
xmlw.WriteStartElement("Starttime");
xmlw.WriteString(DateTime.Now.AddHours(0).ToString());
xmlw.WriteEndElement();
xmlw.WriteStartElement("Changetime");
xmlw.WriteString(DateTime.Now.AddHours(0).ToString());
xmlw.WriteEndElement();
xmlw.WriteStartElement("Endtime");
xmlw.WriteString(DateTime.Now.AddHours(1).ToString());
xmlw.WriteEndElement();
xmlw.WriteEndElement();
xmlw.WriteEndDocument();
xmlw.Close();
XmlDocument doc = new XmlDocument();
doc.Load(@"C:\WINDOWS\Temp\exm.xml");
XmlNode root = doc.DocumentElement["Starttime"];
root.FirstChild.InnerText = "First";
XmlNode root1 = doc.DocumentElement["Changetime"];
root1.FirstChild.InnerText = "Second";
doc.Save(@"C:\WINDOWS\Temp\exm.xml");
Try this. It's C# code.