print "%02d"%a
is the python 2 variant
python 3 uses a somewhat more verbose formatting system:
"{0:0=2d}".format(a)
The relevant doc link for python2 is: http://docs.python.org/2/library/string.html#format-specification-mini-language
For python3, it's http://docs.python.org/3/library/string.html#string-formatting