If you followed the white paper put out by Amazon for installing Postgresql on AWS, which included creating a /data/ directory on a filesystem mounted on a separate EBS volume, then your postgresql.conf file is in /data/
From which I conclude the file is created during initialisation of the data directory, and resides in the root of the data dir. For a default install this appears to be /var/lib/pgsql/data, but not if you moved the data dir