HttpWebRequest request =(HttpWebRequest)WebRequest.Create("some url");
request.Method = "POST";
request.ContentType = "application/x-www-form-urlencoded";
request.UserAgent = "Mozilla/5.0 (compatible; MSIE 9.0; Windows NT 7.1; Trident/5.0)";
request.Accept = "/";
request.UseDefaultCredentials = true;
request.Proxy.Credentials = System.Net.CredentialCache.DefaultCredentials;
doc.Save(request.GetRequestStream());
HttpWebResponse resp = request.GetResponse() as HttpWebResponse;
Hope it helps