A tool with a single solution for this I'm unaware of, but you can use Firebug and Web Developer extension at the same time.
Use Firebug to copy the html section you need (Inspect Element) and Web Developer to see which css is associated with an element (Calling Web Developer "View Style Information" - it works like Firebug's "Inspect Element", but instead of showing the html markup it shows the associated CSS with that markup).
It's not exactly what you want (one click for everything), but it's pretty close, and at least intuitive.