I'm not sure what you mean by a string that contains binary numbers. But for reversing a string (or any STL-compatible container), you can use std::reverse(). std::reverse() operates in place, so you may want to make a copy of the string first:
#include <algorithm>
#include <iostream>
#include <string>
int main()
{
std::string foo("foo");
std::string copy(foo);
std::cout << foo << '\n' << copy << '\n';
std::reverse(copy.begin(), copy.end());
std::cout << foo << '\n' << copy << '\n';
}