I took the above but had to add one more piece because it was putting a space after the hour which gave a syntax error with the rename command. I used:
set HR=%time:~0,2%
set HR=%Hr: =0%
set HR=%HR: =%
rename c:\ops\logs\copyinvoices.log copyinvoices_results_%date:~10,4%-%date:~4,2%-%date:~7,2%_%HR%%time:~3,2%.log
This gave me my format I needed: copyinvoices_results_2013-09-13_0845.log