Actually, the correct way of checking for 32 bit or 64 bit platform is to use the Win64 constant which is defined in all versions of VBA (16 bit, 32 bit, and 64 bit versions).
#If Win64 Then
' Win64=true, Win32=true, Win16= false
#ElseIf Win32 Then
' Win32=true, Win16=false
#Else
' Win16=true
#End If
Source: VBA help on compiler constants