You can use the datapart to maintain time date type and you can compare it to another time.
Check below example:
declare @fromtime time = '09:30'
declare @totime time
SET @totime=CONVERT(TIME, CONCAT(DATEPART(HOUR, GETDATE()),':', DATEPART(MINUTE, GETDATE())))
if @fromtime <= @totime
begin print 'true' end
else begin print 'no' end