[c++] How do I print out the contents of a vector?

You can use an iterator:

std::vector<char> path;
// ...
for (std::vector<char>::const_iterator i = path.begin(); i != path.end(); ++i)
    std::cout << *i << ' ';

If you want to modify the vector's contents in the for loop, then use iterator rather than const_iterator.

But there's lots more that can be said about this. If you just want an answer you can use, then you can stop here; otherwise, read on.

auto (C++11) / typedef / type alias (C++11)

This is not another solution, but a supplement to the above iterator solution. If you are using the C++11 standard (or later), then you can use the auto keyword to help the readability:

for (auto i = path.begin(); i != path.end(); ++i)
    std::cout << *i << ' ';

But the type of i will be non-const (i.e., the compiler will use std::vector<char>::iterator as the type of i).

In this case, you might as well just use a typedef, which also brings with it its own benefits (which I won't expound upon here):

typedef std::vector<char> Path; // 'Path' now a synonym for the vector
Path path;
// ...
for (Path::const_iterator i = path.begin(); i != path.end(); ++i)
    std::cout << *i << ' ';

C++11 also introduced a type alias, which does the same job as a typedef and you may find more readable than using typedef:

using Path = std::vector<char>; // C++11 onwards only
Path path;
// ...
for (Path::const_iterator i = path.begin(); i != path.end(); ++i)
    std::cout << *i << ' ';

counter

You can, of course, use a integer type to record your position in the for loop:

for(int i=0; i<path.size(); ++i)
  std::cout << path[i] << ' ';

If you are going to do this, it's better to use the container's member types, if they are available and appropriate. std::vector has a member type called size_type for this job: it is the type returned by the size method.

// Path typedef'd to std::vector<char>
for( Path::size_type i=0; i<path.size(); ++i)
  std::cout << path[i] << ' ';

Why not just use this over the iterator solution? For simple cases you might as well, but the point is that an iterator is an object designed to do this job for more complicated objects where this solution is not going to be ideal.

range-based for loop (C++11)

See Jefffrey's solution. In C++11 (and later) you can use the new range-based for loop, which looks like this:

for (auto i: path)
  std::cout << i << ' ';

Since path is a vector of items (explicitly std::vector<char>), the object i is of type of the item of the vector (i.e., explicitly, it is of type char). The object i has a value that is a copy of the actual item in the path object. Thus, all changes to i in the loop are not preserved in path itself. Additionally, if you would like to enforce the fact that you don't want to be able to change the copied value of i in the loop, you can force the type of i to be const char like this:

for (const auto i: path)
  std::cout << i << ' ';

If you would like to modify the items in path, you can use a reference:

for (auto& i: path)
  std::cout << i << ' ';

and even if you don't want to modify path, if the copying of objects is expensive you should use a const reference instead of copying by value:

for (const auto& i: path)
  std::cout << i << ' ';

std::copy (C++11)

See Joshua's answer. You can use the STL algorithm std::copy to copy the vector contents onto the output stream. This is an elegant solution if you are comfortable with it. Getting more familiar with STL algorithms should be encouraged, and they provide a lot of functionality that beginners may fall into reinventing themselves. Read Joshua's post for more info.

overload std::ostream::operator<<

See Chris's answer, this is more a complement to the other answers since you will still need to implement one of the solutions above in the overloading. In his example he used a counter in a for loop. For example, this is how you could quickly use Joshua's solution:

#include <iterator> // needed for std::ostram_iterator

template <typename T>
std::ostream& operator<< (std::ostream& out, const std::vector<T>& v) {
  if ( !v.empty() ) {
    out << '[';
    std::copy (v.begin(), v.end(), std::ostream_iterator<T>(out, ", "));
    out << "\b\b]";
  }
  return out;
}

Using any of the other solutions should be equally straightforward.

conclusion

Any of the solutions presented here will work. It's up to you and the code on which one is the "best". Anything more detailed than this is probably best left for another question where the pros/cons can be properly evaluated; but as always user preference will always play a part: none of the solutions presented are wrong, but some will look nicer to each individual coder.

addendum

This is an expanded solution of an earlier one I posted. Since that post kept getting attention, I decided to expand on it and refer to the other excellent solutions that were posted here. My original post had a remark that mentioned that if you were intending on modifying your vector inside a for loop then there are two methods provided by std::vector to access elements: std::vector::operator[] which does not do bounds checking, and std::vector::at which does perform bounds checking. In other words, at will throw if you try to access an element outside the vector and operator[] wouldn't. I only added this comment, originally, for the sake of mentioning something that it might be useful to know of if anyone already didn't. And I see no difference now. Hence this addendum.