[windows] Why does CreateProcess give error 193 (%1 is not a valid Win32 app)

Your Button2Click and Button3Click functions pass klad.xls and smimime.txt. These files most likely aren't actual executables indeed.

In order to open arbitrary files using the application associated with them, use ShellExecute

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Why does CreateProcess give error 193 (%1 is not a valid Win32 app)

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Why does CreateProcess give error 193 (%1 is not a valid Win32 app)