An access violation at anywhere near adress '00000000' indicates a null pointer access. You're using something before it's ever been created, most likely, or after it's been FreeAndNil()'d.
A lot of times this is caused by accessing a component in the wrong place during form creation, or by having your main form try and access something in a datamodule that hasn't been created yet.
MadExcept makes it pretty easy to track these things down, and is free for non-commercial use. (Actually, a commercial use license is pretty inexpensive as well, and well worth the money.)